Stable Phase Equilibrium of the Aqueous Ternary System Li~+//Cl~-,borate- H_2O at 348 K     

WANG Chun  ZENG Ying  HE Zhiyi 《《地质学报》英文版》2014,88(Z1):377-378

正The Sichuan Basin,with an area of about 20×104 km2,is situated at 102.5°~110°E and 27.67°~32.67°N.The underground brine resources in Sichuan basin are a type of comprehensive liquid mineral resource.Pingluo  相似文献   

电离层上行O⁺离子沿不同经度处的磁力线向磁层的传输          下载免费PDF全文

史建魁  李纯强  刘振兴 《地球物理学报》2002,45(3):306-312

根据解析求解引导中心近似的动力学方程得到的离子分布函数 ,研究了不同Kp指数条件下起源于不同电离层区域的上行O⁺离子通量密度沿不同经度处的磁力线的定态分布 ,并研究了上行O⁺离子向不同磁层区域传输的特性 .主要结果为 :（ 1 ）起源于向阳面极光带外侧及更低纬区的电离层离子基本上传输到向阳面磁层区 ;起源于背阳面极光带及更低纬区的电离层离子基本上传输到背阳面磁尾等离子体片区和闭合磁力线区 ;起源于极盖区及向阳面极光带内侧的电离层离子基本上传输到等离子体幔区和磁瓣区 .（ 2 ）上行离子主要分布在近地空间 ,其通量密度相对于地心距离呈负梯度 .（ 3）地磁活动指数Kp 增高时上行离子进入磁层的概率增大 ,因而上行离子起动力学作用的地球空间范围增大 .所得结果可解释有关地顶的观测特征 ,理论估算的上行离子在磁尾的通量密度与观测结果相符合.  相似文献   

乍得湖盆地典型区域降雨入渗补给地下水试验     

危润初  姜颖迪  李铭远  杜成额  乔小坡 《吉林大学学报(地球科学版)》2021,51(2):495-504

针对尼日利亚北部乍得湖盆地降雨入渗补给地下水的问题,选择典型区域开展土壤剖面取样工作,采用氯离子平衡法计算各剖面降雨入渗补给量,并结合野外调查、钻探等工作研究影响降雨入渗补给的主要因素。结果表明：4个取样点（Y₁、Y₂、Y₃、Y₄）土壤剖面年平均降雨入渗补给量分别为4.9、1.5、7.9、26.2 mm/a,平均值为10.1 mm/a,年平均降雨入渗补给率仅为0.72%、0.22%、1.17%、3.87%,平均值为1.49%;研究区降雨入渗补给量很少,降雨对地下水资源的补给有限,地下水的主要补给来源为Hadejia河;研究区蒸散发量大,植物根系发达、吸水能力强,地表入渗水分多在表层土壤中或泥质层与风积砂层交界面上消耗于蒸发蒸腾,最终散失到大气中。在人类活动严重改变Hadejia河水文情势的背景下,研究区这种独特的地下水补给特征导致地下水位快速下降,使得区内正面临较严重的地下水资源枯竭问题。  相似文献   

ZH型重金属螯合纤维对水溶液中Sr²⁺的吸附行为     

周琳  董发勤  张伟  周磊  霍婷婷  聂小琴  周嘉琪  谢陶玲 《岩石矿物学杂志》2018,37(4):679-686

研究了ZH型重金属螯合纤维对水溶液中Sr~(2+)的吸附行为,考察了pH值、纤维加入量、Sr~(2+)初始浓度、作用时间等对吸附行为的影响,并采用SEM、EDS和FTIR等现代分析测试手段探讨了ZH型重金属螯合纤维对Sr~(2+)的吸附机制。结果表明,在pH值为7.0、纤维加入量为2.0 g/L、Sr~(2+)初始质量浓度为50 mg/L的条件下,纤维对Sr~(2+)的吸附在4 h左右基本达到平衡。实验条件下ZH型重金属螯合纤维对Sr~(2+)的最大吸附量可达26.22 mg/g。等温吸附拟合结果表明,ZH型重金属螯合纤维对Sr~(2+)的吸附可能是以单分子层为主的单分子层和多分子层吸附共同作用的结果。纤维对Sr~(2+)的动力学吸附过程符合准二级动力学模型。红外光谱分析表明Sr~(2+)与纤维上—NH_2和—COOH等基团进行配位络合从而吸附在纤维表面,—CH_2—和C=CH_2等基团参与此吸附过程。能谱分析表明Sr~(2+)与纤维上Na~+和Ca~(2+)还存在着离子交换作用。  相似文献   

Effect of Carbonation and Drying-Wetting Cycles on Chloride Diffusion Behavior of Coral Aggregate Seawater Concrete     

DA Bo  LI Yipeng  YU Hongfa  MA Haiyan  CHEN Haoyu  DOU Xuemei  WU Zhangyu 《中国海洋大学学报(英文版)》2022,21(1):113-123

Based on seawater immersion,drying-wetting cycles,carbonation and drying-wetting cycles for coral aggregate sea-water concrete(CASC)with different strength grades,the effect of carbonation and drying-wetting cycles on chloride diffusion be-havior of CASC is studied.The results show that the free surface chloride concentration(Cs),free chloride diffusion coefficient(Df)and time-dependent index(m)of CASC in the drying-wetting cycles is obviously higher than that in seawater immersion.The Df and m of CASC of carbonation and drying-wetting cycles is higher than that in the drying-wetting cycles.Carbonation increases the Df and m of CASC,which is against CASC to resist chloride corrosion.The corrosion possibility of CASC structures in different ex-posed areas is as follows:splash zone(carbonation and drying-wetting cycles)>tidal zone(drying-wetting cycles)>underwater zone(seawater immersion).Besides,the chloride diffusion rate of C65-CASC is 17.8%-63.4%higher than that of C65-ordinary aggre-gate concrete(OAC)in seawater immersion(underwater zone).Therefore,anti-corrosion measures should be adopted to improve the service life of CASC structure in the oceanic environment.  相似文献   

三元体系CaCl₂-SrCl₂-H₂O相平衡在高钙锶比卤水体系中分离提取氯化锶的应用          下载免费PDF全文

韩海军  吉祥  陈烽雄  李家乐  黄军榜 《盐湖研究》2022,30(4):154-160, 153

采用等温溶解平衡法测定了三元体系CaCl₂-SrCl₂-H₂O温度在353.15 K时共饱和点的溶解度。基于实验结果和文献已有报道的该体系多温下的相平衡数据,模拟了南翼山油田卤水中氯化钙和氯化锶在温度323.15 K下的分离实验。模拟钙锶分离实验结果表明,物质的量比为25.41∶1的CaCl₂和SrCl₂的混合溶液在323.15 K下蒸发结晶提纯后的固相中钙锶物质的量比降低为1.73∶1,SrCl₂的回收率为52.47%,将所得一次固相产品在323.15 K下溶解并再次蒸发后,钙和锶的物质的量比从1.73∶1降至1.1∶1,SrCl₂的回收率为78.67%,SrCl₂的总回收率为41.28%。  相似文献   

地衣芽孢杆菌(Bacillus licheniformis)对镉胁迫下泥蚶(Tegillarca granosa)的抗氧化酶活性和免疫相关基因表达的影响     

王稷  李晔  瞿洋  沈灵灵  孙静  全晶晶 《海洋与湖沼》2014,45(5):1058-1063

本文研究一株地衣芽孢杆菌(Bacillus licheniformis)对提高泥蚶耐受镉(Cd2+)胁迫的作用,实验分析了不同浓度地衣芽孢杆菌对Cd2+胁迫下泥蚶(Tegillarca granosa)的存活率及组织中Cd残留量的影响;同时比较了地衣芽孢杆菌作用前后,泥蚶体内两类抗氧化酶,超氧化物歧化酶(SOD)和谷胱甘肽过氧化物酶(GSH-Px)的活性,进一步通过Real-time PCR分析了三类免疫相关基因金属硫蛋白(MT)、小热休克蛋白分子(sHSP)和铁蛋白(ferritin)的表达情况。研究结果显示,地衣芽孢杆菌能降低泥蚶组织中Cd残留量,提高其存活率。并能有效促进泥蚶体内SOD和GSH-Px酶活性的增加,同时降低MT、sHSP和ferritin在mRNA水平上的表达。数据表明该地衣芽胞杆菌可通过调节泥蚶的免疫系统,起到降低Cd2+对泥蚶毒害的作用。  相似文献   

A Method for Rapid Determination of Re and Os Isotope Compositions Using ID‐MC‐ICP‐MS Combined with the Sparging Method     

Tatsuo Nozaki  Katsuhiko Suzuki  Gregory Ravizza  Jun‐Ichi Kimura  Qing Chang 《Geostandards and Geoanalytical Research》2012,36(2):131-148

A simple, rapid method for the determination of Re and Os concentrations and isotope compositions using isotope dilution multi‐collector inductively coupled plasma‐mass spectrometry (ID‐MC‐ICP‐MS) combined with Carius tube digestion and sparging introduction of Os was developed. For Os measurement, four channeltron ion counters to detect different Os isotopes were used simultaneously, which led to a drastic reduction in the measurement time. Rhenium isotopes were measured by means of eight Faraday cups with solution nebulisation and an ultrasonic membrane desolvator. The representative ¹⁸⁸Os count rate of an Os standard solution containing 50 pg of total Os was approximately 110000–120000 cps at the onset of measurement; the Re intensity of our in‐house 10 pg g^?1 standard solution reached 1820 V/μg g^?1 with a sample uptake rate of 95–99 μl min^?1. These values indicate that the sensitivity of the method was sufficient even for samples with low Re and Os concentrations, such as chert. As the temporal variations of the amplification efficiency of the ion counters differed from one another, we adopted a sample‐calibrator bracketing method to correct the measured Re and Os isotope ratios. The Re and Os concentrations via the isotope dilution method and the ¹⁸⁷Os/¹⁸⁸Os ratios of two sedimentary rock reference materials (JMS‐2 and JCh‐1) on the basis of the isotope ratios determined by the MC‐ICP‐MS and by negative thermal ionisation mass spectrometry (N‐TIMS) were comparable within their ranges. Based on Os isotope measurement of the IAG reference material [Durham Romil Os (DROsS)], the average difference from the recommended value and precision of Os isotope measurements by the sparging method in combination with multi‐ion‐counters were 0.72% and 0.76% [1RSD (%), n = 29], respectively. The precisions in the ¹⁸⁷Os/¹⁸⁸Os ratios [1RSD (%)] of JMS‐2, JCh‐1 and DROsS were 0.35–0.71, 1.56–3.31 and 0.99–1.28%, respectively, which depended on their Os ion intensities. No systematic difference was observed between the Re and Os geochemical compositions of JCh‐1 and JMS‐2 obtained by means of digestion with inverse aqua regia and CrO₃‐H₂SO₄ solutions, suggesting that either acid solution can be used for the sparging method of sedimentary rock samples. As CrO₃‐H₂SO₄ solution is believed to liberate predominantly the hydrogenous Re and Os fraction from organic‐rich sediment, the sparging method combined with CrO₃‐H₂SO₄ digestion and multi‐ion‐counters in the mass spectrometry is expected to be a powerful tool for reconstructing the secular change in marine Os isotope compositions with high sample throughput.  相似文献   

Accurate Measurement of Rare Earth Elements by ICP‐MS after Ion‐Exchange Separation: Application to Ultra‐Depleted Samples     

Marc Ulrich  Sarah Bureau  Catherine Chauvel  Christian Picard 《Geostandards and Geoanalytical Research》2012,36(1):7-20

This study reports precise and accurate data for rare earth elements (REE) measured on eight geological reference materials, five enriched in REE (BE‐N, BHVO‐2, BR, BR‐24 and RGM‐1) and three very depleted in REE (BIR‐1, UB‐N and DTS‐2). Data were acquired by quadrupole ICP‐MS after isolation of the REE using an ion‐exchange chromatography procedure. All the measured REE abundances were similar within ≈ 5% (10% for the most REE‐depleted sample DTS‐2) to the high‐quality measurements previously published in the literature. We also show that by using an internal Tm spike, the reproducibility of the data was improved to ～ 1%. Applying this technique to the analysis of ultra‐depleted rock samples (sub ng g^?1), we show that significant improvements were obtained relative to the routine trace element measurement method. The chondrite‐normalised patterns were smooth instead of displaying irregularities. Although the classical method gives excellent results on REE‐rich samples, we believe that our technique improves the precision and accuracy of measurements for highly REE‐depleted rocks.  相似文献   

天津滨海土壤盐分离子相关性及采样密度研究   总被引：1，自引：0，他引：1       下载免费PDF全文

李攻科  王卫星  曹淑萍  程绪江  刘永涛  张亚娜 《中国地质》2016,(2):662-670

土壤盐渍化是一个世界性的生态问题。天津滨海地区土壤长期遭受海水及高矿化潜水共同作用,土壤盐渍化现象分布广泛。本文选取天津滨海新区太平镇作为典型地区,研究了土壤主要盐分离子的相关性,另外对工作区采样点进行了随机均匀抽稀试验,探讨了不同采样密度对土壤盐渍化插值结果和评价结果的影响。研究表明:天津滨海地区土壤易溶盐中Na+、Cl-所占比例具有绝对优势;土壤中全Cl、Cl-与全盐量具有非常好的相关性,随机均匀抽取少量样本加测全盐量,建立全Cl与全盐量的相关方程可以比较准确地推算出所有样本的全盐量;大密度采样有利于提高样本的代表性,若要满足相对误差合格率≥80%的要求,采样密度不应低于4点/km2,另外用于评价盐渍化等级的采样密度不宜低于1点/km2。  相似文献